All five people in the Cruze were taken to Miami Valley Hospital, including a 3-year-old that suffered a head laceration.
Paulin said the driver of the Cruze, a 26-year-old woman, has been cited for failing to yield.
A woman riding as a passenger in the van was taken by CareFlight to Miami Valley. She has been treated and released.
There was also a 3-year-old in the back seat of the van.
No one suffered life-threatening injuries as a result of the crash.
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